Octahedral cobalt(III) complexes of the chloropentammine type. XVII. Association and reaction of some halogenopentamminecobalt(III) and halogenopentamminechromium(III) cations with hydroxide in aqueous dioxan
Abstract:The replacement, by hydroxide ion, of the coordinated halide from some halogenopentamminecobalt(III) and ‐Chromium(III) cations in aqueous dioxan has been studied over a range of alkali concentrations up to 0.1 M. With excess of hydroxide ion at constant ionic strength, pseudo first‐order rate constants were obtained. The results support a pre‐equilibrium association of complex and hydroxide ions in these media, but do not provide distinction as to whether the resulting ion‐pair subsequently reacts by direct e… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.