1995
DOI: 10.1103/physrevlett.74.734
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Observation of the Sliding Mode in Incommensurate Intergrowth Compounds: Brillouin Scattering from the Inclusion Compound of Urea and Heptadecane

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Cited by 49 publications
(27 citation statements)
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“…The results obtained are very helpful when discussing the possibility of existence of the so-called sliding mode in the incommensurate inclusion compounds. As follows from our experiment, the velocity of the γ S mode is lower than that of the transverse mode γ 9, which is in contradiction to the results obtained for the urea/C 17 H 36 system [11], however, it may indicate the possibility of existence of some collective excitations not only along the guest chains. The application of pressure of an order of a few ten bars was proved to lead to disappearance of the γ S mode.…”
Section: Discussioncontrasting
confidence: 84%
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“…The results obtained are very helpful when discussing the possibility of existence of the so-called sliding mode in the incommensurate inclusion compounds. As follows from our experiment, the velocity of the γ S mode is lower than that of the transverse mode γ 9, which is in contradiction to the results obtained for the urea/C 17 H 36 system [11], however, it may indicate the possibility of existence of some collective excitations not only along the guest chains. The application of pressure of an order of a few ten bars was proved to lead to disappearance of the γ S mode.…”
Section: Discussioncontrasting
confidence: 84%
“…Discussion on a possibility of appearance of a sliding mode in the Brillouin spectra started in 1995 when Schmicker et al reported [11] the observation of such an excitation in CO(NH 2 )/C 17 H 36 clathrate. The authors [11] attributed the Brillouin mode of a frequency of about 15 GHz to the vibration of the guest sublattice.…”
Section: Excessive Phonon Excitations and The Concept Of The Sliding mentioning
confidence: 97%
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“…The expressions relating the phonon and phason speed of sound to the relative density and rigidity of the subsystems may be directly used for analysing existing available data for light scattering on these compounds (Schmicker et al 1995). These experiments seem to prove the existence of an unpinned phason mode having low damping.…”
Section: Discussionmentioning
confidence: 99%
“…In general terms, such materials can be subdivided into two types, depending on whether the ratio of the guest and host periodicities, α = c g /c h , is rational or irrational. In the case of rational α, the material is classified as commensurate, whereas in the case of irrational α, the material is classified as incommensurate [23][24][25][26]. For urea inclusion compounds, the relationship between c g and c h is usually incommensurate, although for certain types of guest molecule, the structure is observed to be commensurate [27][28][29].…”
Section: (A) Solid Inclusion Compoundsmentioning
confidence: 99%