Understanding thermomagnetic phase transitions in frustrated
magnetic
materials is a complex problem. Herein, we study the canted antiferromagnet
pyrochlore (α-Cu2V2O7) and
uncover a second-order phase transition (SOPT) through magnetocaloric
effect. The corroboration for this transition is rationalized by qualitative
and quantitative magnetic data analysis. The first-order phase transition
is ruled out owing to the extinction of thermal hysteresis and the
existence of positive slopes in H/M vs M2 Arrott plots,
in agreement with Banerjee criterion. The manifestation of a “caret”
type shape, a fingerprint of SOPT, in the three-dimensional plots
of temperature evolution of entropy change (ΔSM)
with the applied field (H) is observed. Captivatingly, the locally
assessed H and T dependence of
n
false(
T
,
H
false)
=
d
ln
false|
normalΔ
S
M
false|
d
ln
H
curves follow n ∼ 1 at lower T,
n ∼ 2 at higher T, and a minimum value at TN. But
just after the TN, the value of n(T,H) is noticed to not
exceed 2, evidently expounding the SOPT, and it is concomitant with
qualitative analysis. From a future perspective, the experimental
techniques can be exploited to study the phase transition along the
different orientations of diverse frustrated magnetic materials in
epitaxial thin films or single crystals that could exhibit appealing
magnetic phenomena.