The structure of 83 As, 85 As and 87 As have been studied in fusion-fission reaction 238 U+ 9 Be. Fission fragments were identified in mass and atomic number using the VAMOS++ spectrometer and the coincident γ-rays were detected in the γ-ray tracking array AGATA. New transitions in 83 As and 85 As are reported and placed in the level schemes. A level scheme of the excited states in 87 As is proposed for the first time. The data are interpreted in frame of Large-Scale Shell-Model calculations, SU3 symmetries and Beyond Mean-Field frameworks. A spherical regime at magic number N =50 is predicted and the location of the proton g 9/2 orbital is proposed for the first time. Development of collectivity in a prolate deformed, γ-soft regime in the open shell cases 85 As and 87 As, most neutron-rich isotopes beyond N =50, is concluded. Data and theoretical calculations give confidence to a relatively high extrapolated excitation energy about 4 MeV of the 9/2 + state in 79 Cu, one proton above 78 Ni.