We have investigated Ba high-I 8snl double Rydberg states produced by multistep laser excitation in the presence of a temporarily applied electric field to probe the Coulomb interaction between the two excited electrons. The spectra for the 6s~8s excitation with n -13 (I = 12 to 6) show a strong dependence on the orbital momentum of the external electron, due to multipole effects. To explain the 5fn'!' resonances appearing in the n = 13 and 14 l =6 spectra, terms higher than the dipole interaction have to be considered in the multipole expansion.PACS number(s): 31. 20.Tz, 31.50.+w, 32.80.Rm The study of electron correlation effects in doubly excited states presents a particularly exciting problem in atomic physics. Because of the nonseparability of its Hamiltonian, the three-body problem cannot be solved easily except when the electrons are asymmetrically excited. Then they are located at different radii ( ( r, ) (((r 2 ) ) and considered as distinguishable particles with negligible exchange effects. In the case of core penetrating low-l orbits, the spectra are dominated by the properties of the intershell states (N, l, n 212 ) inside a non-Coulombic reaction zone. These states are well described outside of it in the framework of the quantumdefect theory [1], where the long-range electronic interactions are in general neglected. This is no longer valid when the electrons are in a planetary situation [2] because of their weaker penetration in the positive doubly charged core. The electron-electron and electron-core interactions may be comparable; recent calculations [3] for a three-body Coulomb system give new insights into the problem. Electronic correlation studies in highly doubly excited atoms in the different situations schematically described above have been reported previously. These range from the pure three-body Coulomb systems He [4,5] and H [6] to non-Coulombic ones involving electronic collision excitation in He [7,8] and sequential laser excitation of both electrons in alkaline-earth-metal atoms [9 -15]. To overcome the autoionization broadening of the lines, doubly excited states with a non-core-penetrating high-l outer electron were produced by an electric-field switching method [16,17]. The results indicated an n dependence and a rapid decrease with l of the autoionization rates due to the centrifugal barrier potential, which prevents penetration of the nl electron inside the residual core. In this case, the outermost electron moves approximately in a hydrogenic orbit around a singly charged core. Then, the anisotropic part of the Coulombic electron-electron interaction can be written, assuming r& (r2 as [18] 1/r&& -1/r2= g r&qr&~~+ "C (8&, p&)C (82, y&), q=1 where the Ct(8, y) are q rank tensorial operators. The total Hamiltonian, including the spin-orbit interaction of the inner X,l, electron but neglecting that of the outer one, commutes with E and K, as well as the parity operator. Here E denotes the coupled angular momenturn between the total angular momentum j, of the Ba+(N, l, ) core and ...