2022
DOI: 10.48550/arxiv.2201.05330
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Observation of anomalous amplitude modes in the kagome metal CsV$_3$Sb$_5$

Gan Liu,
Xinran Ma,
Kuanyu He
et al.

Abstract: We report Raman scattering spectroscopy of the kagome metal CsV3Sb5 to investigate its chargedensity wave (CDW) phase. Temperature-dependent measurements reveal a multitude of CDWinduced modes, in agreement with density-functional theory calculations assuming the inverse Star of David lattice distortion. They are shown to be strongly hybridized amplitude modes and zonefolded modes, different from those in other known CDW materials. These CDW modes show negligible magnetic-field dependence and a signature of c-… Show more

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Cited by 4 publications
(3 citation statements)
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“…In addition, recent Raman spectroscopy reported the anomalous amplitude modes in the absence of soft phonons, indicating that the CDW exhibits the character of strong electron-phonon coupling. [61] In the phonon spectroscopy, the structural change shows a predominately first-order phase transition. No CDW amplitude mode is identified in the ordered phase.…”
Section: The 2 × 2 Superlattice Charge Orders In Kagome Latticementioning
confidence: 99%
“…In addition, recent Raman spectroscopy reported the anomalous amplitude modes in the absence of soft phonons, indicating that the CDW exhibits the character of strong electron-phonon coupling. [61] In the phonon spectroscopy, the structural change shows a predominately first-order phase transition. No CDW amplitude mode is identified in the ordered phase.…”
Section: The 2 × 2 Superlattice Charge Orders In Kagome Latticementioning
confidence: 99%
“…Polarized Raman spectroscopy of CsV 3 Sb 5 uncovers a phonon anomaly below ( 50 K) and at the CDW transition temperature ( 94 K), which is attributed to secondary electronic instabilities in the CDW state with s-wave symmetry. 62 Thickness-dependent Raman spectroscopy measurements on CsV 3 Sb 5 63 demonstrate enhanced changes in phonon properties as the thickness decreases, which highlights large electron-phonon coupling. More recently, studies from temperature-dependent x-ray diffraction, 64,65 polarization-resolved electronic Raman spectroscopy, 66 and ARPES 67 reveal the existence of a 2 Â 2 Â 4 superstructure in CsV 3 Sb 5 at higher temperatures in contrast to the 2 Â 2 Â 2 superstructure at lower temperatures.…”
Section: Journal Of Applied Physicsmentioning
confidence: 97%
“…Focusing on the case of CsV 3 Sb 5 , several recent studies have investigated its electronic ordering instability, a CDW that is associated with a magnetic susceptibility anomaly at T CDW = 94 K [14][15][16][17]. Somewhat surprisingly the CDW order in CsV 3 Sb 5 is three-dimensional [3,5,8,[18][19][20][21], which means that there are electron correlations not only in the kagome plane (ab-plane), but also between the kagome layers, along the c-axis.…”
mentioning
confidence: 99%