“…In fact, in a semi-infinite solid, if the process goes on long enough, the pyrolysis layer will no longer be near the heated surface and then the transport of the pyrolysis gas in the char matrix should be accounted for. Some models 16–18 have treated the flowing of pyrolysis gas using Darcy’s law, which indicates that the flowing of volatile is driven by a pressure gradient. However, Zhou et al 7 and Kashiwagi 8 both indicated that radiation absorption by pyrolysis gas is significant, so radiation attenuation in horizontal and vertical sample orientations are significantly different owing to the different structure of the plume.…”