Numerical simulations of the oxygen production in the oscillating Bray–Liebhafsky reaction

Studies of visible oscillating chemiluminescence in luminol–H2O2–KSCN–CuSO4 system using (2‐hydroxyethyl) trimethylammonium hydroxide

“…monotonic, regular oscillations, quasiperiodicity, chaotic (5)(6)(7)(8). Among them, only monotonic regimes are widely used in kinetic methods for chemical analysis (9)(10)(11). These methods are based on the ability of a substance to change the kinetics of a chemical reaction.…”

Quantitative determination of some water-soluble B vitamins by kinetic analytical method based on the perturbation of an oscillatory reaction

“…According to the obtained experimental results and knowing that reduced form of vitamin B 2 (B 2red ) can be oxidized with O 2 through a complex mechanism resulting in oxidized riboflavin (B 2ox ) and hydrogen peroxide, 56 we conclude that the main active specie in our system is hydrogen peroxide that is got from riboflavin peroxide. Having this in mind, as well as that in BL reaction a continuous production of oxygen occurs, 57,58 we suggest that following reactions play an crucial role in the examined system:…”

Mechanism and Phenomenology of an Oscillating Chemical Reaction

“…Degn, Liebhafsky, Noyes and others have investigated the BL reaction, but the overall mechanism has still has not been fully elucidated, and is complicated by the fact the system is also sensitive to light and oxygen. The kinetics of the two processes have recently been re-investigated by Schmitz who has also proposed a 6-step model [172] which reproduces the main features reasonably well [173], but is an oversimplification of the system. The above reaction oscillates in batch at temperatures in excess of 50°C.…”