We introduce ethyl acetate (EA), a bio-based chemical, as a potential solvent for bitumen recovery through comprehensive phase behavior and numerical simulation studies. Phase behavior and thermophysical properties of EA/live bitumen are measured at temperatures and pressures up to 190 C and 4 MPa, respectively. Experimental studies suggested that coinjection of EA with steam can reduce the bitumen viscosity by several orders of magnitude. Our numerical simulations show that coinjection of 2-8 mol% EA with steam can significantly reduce the steam-oil-ratio (SOR) by almost 0.9 units while increasing the bitumen production rate. This reduction in SOR can be translated to significant energy saving of~2.2 GJ, emission reduction of~120 kg of CO 2 , and wastewater reduction of~120 m 3 per ton of the produced bitumen, which are almost 20-25% lower than the steam-assisted gravity drainage (SAGD) process.