Liquid−liquid systems research increasingly concentrates on computer simulations. However,
the possibility of adequately testing complex theoretical models against experiments is hindered
by a lack of reliable reproducibility data for laboratory and pilot-plant measurements. This
strongly limits meaningful evaluation of the increasingly complex process and equipment models/algorithms that are being developed. In this work, experimental data are obtained in a pilot-scale Kühni column, and model parameters and simulated data are generated using a drop
population balance model and algorithm. The results can be summarized as follows: (i) As
measured by the magnitude of careful random error and corresponding confidence limits
estimates, the simulation results exhibit excellent agreement with experimental drop-size
distributions and fair conformity with measured dispersed-phase hold-ups. (ii) Both experimental
and simulated results show that interdrop coalescence is always present within a column
extractor, even at low dispersed-phase hold-ups, and thus cannot be neglected in any physically
realistic and accurate modeling.