Inkjet printing has the advantages of high material utilization,
low cost, and large-area production and is a promising manufacturing
technology for organic light-emitting diode (OLED) displays. However,
the droplet evaporation in micron-size pixel pits is highly influenced
by the pit wall. Such a process is extremely difficult to control,
leading to the appearance of defects such as the coffee ring in the
printing process of OLED displays. In this work, a multiphase thermal
lattice Boltzmann (LB) model based on multiple distribution functions
is established to study the evaporation process of micron-size droplets
in pits. According to the characteristics of the largest number of
the three-phase contact line (TCL) appearing in the evaporation process,
the evaporation modes can be divided into three types, i.e., one,
two, and three TCLs. In the 1-TCL mode, the droplet stays in constant
contact radius (CCR) for the shortest time; in 2-TCL and 3-TCL modes,
the liquid film fracture behavior of evaporating droplets in the pit
is well captured. The effects of the pit height and the contact angle
on the droplet evaporation mode are investigated in detail. The phase
diagrams of evaporation modes with different parameters are also established.
The revealed evaporation mechanism is supposed to be useful for regulating
the droplet evaporation behavior and controlling the cured film shape
in the OLED printing process.