“…The rich variety of invasion patterns has been extensively characterized experimentally, and through simulations at the pore scale [67,23,55,85,56,68,58,43,69]. The classical macroscopic (continuum) models of multiphase flow in porous media, based on phase balance equations, generalizations of Darcy's law, and constitutive relationships for relative permeability and capillary pressure, are unable to explain these flow patterns in immiscible flow [38,79,65,1]. New macroscopic theories of flow of mixtures in porous media will emerge in the next few years, and most likely the mathematical structure of these new models will resemble that of models of phase transitions and surface growth [24].…”