“…connected to tile drains, for instance, may be most important in terms of the rapid movement of land-surface-derived contaminants to subsurface water flow systems (e.g., tile drains) (Fleming and Bradshaw, 1992;Fox et al, 2004;Akay and Fox, 2007;Frey et al, 2016). A substantial body of literature has been produced regarding N transformations and transport in agricultural soils (i.e., Lee et al, 2006;Berlin et al, 2013Berlin et al, , 2014aLi et al, 2015). And while some studies have characterized or modeled macropore connectivity in soil in the context of flow (Akay et al, 2008;Klaus and Zehe, 2010), there is a need to elucidate dynamic chemical transformations and transport in soil macropores under various degrees of macropore connectivity (Jarvis et al, 2017).…”