“…Different authors have tried to model the treatment and the whole process [8,10,18,19,21,39,[41][42][43][44], but it has not been still possible to find accurate model. Literature data from research and applications indicate that about 50% of the total chloride content can be removed [17,45].…”
“…Different authors have tried to model the treatment and the whole process [8,10,18,19,21,39,[41][42][43][44], but it has not been still possible to find accurate model. Literature data from research and applications indicate that about 50% of the total chloride content can be removed [17,45].…”
“…Sa'id-Shawqi et al [122] used the Nernst-Planck and Laplace (potential and current distributions determination) equations to predict the amount of extracted chloride and the remaining chloride profile in a ECE treatment (voltage mode). The study solely considered free chloride removal from concrete.…”
“…In the chloride extraction model-similarly in works (Andrade et al 1995;Sa'Id-Shawqi et al 1998;Castellotte et al 1999Castellotte et al , 2000-it is assumed that migration of ions under the influence of an electric field is the most important mechanism.…”
Section: Description Of the Process And Model Simplificationsmentioning
confidence: 99%
“…On the basis of Nernst-Planck and Nerst-Eistein equations the theoretical model which describes the jet of ion mass in an electrolyte solution was created (Andrade et al 1995;Sa'Id-Shawqi et al 1998;Castellotte et al 1999Castellotte et al , 2000. These equations are correct in a diluted solution and determine the flow of only one component.…”
During the extraction of chlorides from concrete there occur processes involving transfer of mass and electric charge via pore solution components. On the basis of the relations which exist between the concentrations of these components, the electric field intensity, the temperature, and the mechanical stress, thermomechanics equations of a multicomponent medium have been used for analytical description. On the basis of equations for the balance of mass, electric charge, momentum, energy and entropy inequality, equations of ion flows have been determined, which are justified in the general effect of the electric field action on the concrete covering. The occurrence of processes which are recognised as dominant ones during the chloride extraction has allowed us to significantly simplify the equations and reduce them to formulas permitting a practical use. By approximating the electrochemical potentials of the leading ions via the linear function of concentration and electric field potential, a flow equation has been determined which has a shape similar to the classical diffusion equation. In order to define the electrodiffusion coefficient occurring in this equation an inverse problem has been formulated and then numerical values of this coefficient have been evaluated using the results of experimental tests.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.