There are many integral transforms that are widely used to solve numerous real-life, science, and engineering problems. In this article, we present SEE transform for determining the solution of the system of linear Volterra integro-differential equations of the second kind. Some applications have been given and solved by using the SEE transform for illustrating the applicability of the SEE transform. Results of the applications assert that the SEE transform is very effective for obtaining the exact solution of this equation.