This paper presents a microscale
modeling approach for investigation of bubble dynamics in the aluminum
smelting process. The motion of a single bubble has been studied through
a computational fluid dynamics (CFD) model facilitated with the volume-of-fluid
(VOF) method to capture the bubble shapes. Using a two-dimensional
geometry of part of a real cell as the testing bed, the motion of
different sized bubbles has been simulated in an air–water
system and a CO2–cryolite system. Comparisons between
the two systems are conducted through the three periods of bubble
motion: bubble sliding under the anode, bubble releasing at the anode
edge, and bubble rising in the side channel. It was found that both
systems show similar trends in bubble dynamics, such as an increase
in the bubble sliding velocity as the bubble size increases and the
appearance of a thick head at large bubble sizes. Quantitatively,
there are differences between the two systems, evidenced in terms
of the detailed bubble dynamics at each period of bubble motion, such
as the bubble morphology, the bubble sliding velocity, the bubble
layer thickness, and the bubble-induced liquid flow. The detailed
microscale modeling provides useful information for the development
of a multiscale modeling methodology by building constitutive correlations
to support the macro/process scale modeling.