This study examines the impacts of thermal stratification and chemical reaction on magnetohydrodynamic (MHD) free convective flow along an accelerated vertical plate with variable temperature and exponential mass diffusion, set within a porous medium. Analytical solutions, utilized, are obtained through the Laplace transform technique to accurately represent the flow's physical mechanism. The research employs advanced mathematical models to analyze the intricate interplay between MHD and convective processes under varying thermal and exponential mass diffusion conditions, offering insights into fluid dynamics that closely simulate real‐world conditions. The study draws a significant conclusion by contrasting the effects of thermal stratification with a nonstratified environment. It has been noted that when stratification is applied to the flow, the steady state is achieved more quickly. The study reveals that thermal stratification reduces fluid velocity and temperature but increases skin friction and the Nusselt number, diverging from nonstratified conditions. It also shows that parameters, like, , and significantly influence velocity, temperature, and concentration in fluid dynamics. This research could be driven by a need to enhance the understanding of fluid flow in various engineering and environmental contexts, where such conditions are prevalent, including geothermal energy extraction, thermal management, chemical processing industries, and environmental control technologies. This novel approach enhances understanding of flow processes in both natural and engineered porous environments.