Numerical and statistical determinations of the controlling factors in biomass-derived alcohol dehydration over La-incorporated γ-Al2O3 catalysts

Hidajat, Marcel Jonathan; Yun, Gwang-Nam; Hwang, Dong Won

doi:10.1016/j.cej.2023.145376

Cited by 4 publications

(1 citation statement)

References 72 publications

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“…Hidajat et al, (2023) used Lanthanum (La)-incorporated γ-Alumina (Al 2 O 3 ) catalyst to produce α-olefin from biomass-derived alcohol. [42] The alcohols generated through FT synthesis are primarily of a primary nature and, in theory, have the potential to undergo a transformation into α-olefins, which are considered valuable olefins. However, when acid catalysts are present, a notable fraction of these olefins undergo isomerization, converting into internal olefins, which possess greater thermodynamic stability.…”

Section: Value-added Products (Olefin) From the Light Petroleum Fract...mentioning

confidence: 99%

Prospect of Controlled Autoxidation to Produce High‐Value Products from the Low‐Value Petroleum Fractions

Siddiquee

2024

The Chemical Record

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Substantial amounts of low‐value light petroleum fractions and low‐value heavy petroleum fractions, such as light naphtha, HVGO, and vacuum residue, are generated during the upgrading and refining of conventional and unconventional petroleum resources. The oil industry emphasizes economic diversification, aiming to produce high‐value products from these low petroleum fractions through cost‐effective and sustainable methods. Controlled autoxidation (oxidation with air) has the potential to produce industrially important oxygenates, including alcohols, and ketones, from the low‐value light petroleum fractions. The produced alcohols can also be converted to olefin through catalytic dehydration. Following controlled autoxidation, the low‐value heavy petroleum fractions can be utilized to produce value‐added products, including carbon fiber precursors. It would reduce the production cost of a highly demandable product, carbon fiber. This review highlights the prospect of developing an alternative, sustainable, and economic method to produce value‐added products from the low‐value petroleum fractions following a controlled autoxidation approach.

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Section: Value-added Products (Olefin) From the Light Petroleum Fract...mentioning

confidence: 99%

Prospect of Controlled Autoxidation to Produce High‐Value Products from the Low‐Value Petroleum Fractions

Siddiquee

2024

The Chemical Record

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Zirconia-incorporated yttria with a Lewis pair of acid–base surface sites for chemoselective dehydration of alcohols into alpha olefins

Lee,

Kim,

Park

et al. 2024

Applied Catalysis A: General

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Efficient production of jet-fuel precursors via one-pot dehydration-oligomerization of higher alcohols from upgrading of bioethanol

Liu,

Liao,

Gong

et al. 2024

Energy Conversion and Management

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Numerical and statistical determinations of the controlling factors in biomass-derived alcohol dehydration over La-incorporated γ-Al2O3 catalysts

Cited by 4 publications

References 72 publications

Prospect of Controlled Autoxidation to Produce High‐Value Products from the Low‐Value Petroleum Fractions

Prospect of Controlled Autoxidation to Produce High‐Value Products from the Low‐Value Petroleum Fractions

Zirconia-incorporated yttria with a Lewis pair of acid–base surface sites for chemoselective dehydration of alcohols into alpha olefins

Efficient production of jet-fuel precursors via one-pot dehydration-oligomerization of higher alcohols from upgrading of bioethanol

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