Numerical Analysis of The Temperature Characteristics of a Coal—Supercritical Water-Fluidized Bed Reactor for Hydrogen Production

Abstract

Supercritical water gasification (SCWG) of coal is a promising clean coal technology, which discards the traditional coal combustion and oxidation reaction to release carbon dioxide and other pollutants and replaces coal with a gasification reduction reaction in supercritical water to finally convert coal into a hydrogen-rich gas product with no net carbon dioxide emissions and no pollutant emissions, and thus has received much attention in recent years. However, the experimental conditions of coal to the hydrogen reactor are harsh, costly, and not easy to visualize and analyze, so numerical calculation and simulation analysis are important for the design, optimization, and industrial scaling-up of the reactor. In order to study the effect of the temperature field on the hydrogen production rate of the coal supercritical water gasification hydrogen production reactor, a numerical simulation calculation model is developed for this reactor in this paper. Comparing the experimental data in the literature, the maximum relative error of the gasification product yield per kg of coal between the two is less than 5%, which verifies the accuracy of the model built and the numerical method adopted in this paper. On this basis, the effects of supercritical water temperature and coal slurry temperature on the reactor’s gasification products and reaction rate were investigated in depth. The results show that increasing the supercritical water temperature is beneficial to improve the reactor hydrogen production efficiency, while the high coal slurry temperature is not conducive to adequate reaction, thus reducing the hydrogen production efficiency. For the laboratory coal supercritical water gasification to hydrogen reactor studied in this paper, the ideal temperature of supercritical water is 850~900 K, and the ideal temperature of coal slurry is 400–450 K. The conclusions of this paper can provide some reference for subsequent industrial scale-up studies of the reactor.

Experimental Investigation of the Effects of Inorganic Components on the Supercritical Water Gasification of Semi-Coke

“…This enables SCW to achieve low mass resistance, high solubility of produced gases, easy separation of salts and impurities, and high reaction rate when used as a gasification medium [9,10]. In recent years, the supercritical water gasification (SCWG) of coal, a novel coal gasification technology, has received extensive attention and in-depth research due to its clean, efficient, and low-cost characteristics [11][12][13][14][15][16][17]. In the SCWG of coal, elements such as C, H, and O will be converted into gas-phase products, mainly existing in the form of H 2 and CO 2 [18].…”