Nucleation, growth, and coarsening of crystalline domains in order-order transitions between lamellar and hexagonal phases

Abstract

Using the numerical solution of the time-dependent Ginzburg-Landau equation, we study the entire process of transformation between the lamellar and the hexagonal phases from the early-stage nucleation and growth to the late-stage coarsening regime. The metastable crystalline structure that nucleates first is identified in terms of the mean-field theory under the single-wave-number approximation. This has been borne out by the numerically efficient preparation of single-crystal structure developed via the noise-induced self-organization. We also present results for the scaling of the late-time domain growth, which is quantified by two measures: the structure factor and the orientational correlation function. In particular, the growth exponent is shown to be robust and indifferent to conservation of the order parameter.