Nuclear Magnetic Resonance Spectrum of Liquid VCl4

Pratt, David W.; Myers, Rollie J.

doi:10.1063/1.1670849

Cited by 5 publications

(1 citation statement)

References 6 publications

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“…The vanadium tetrachloride molecule has one unpaired electron and is a liquid at room temperature with enough vapor pressure to make it a candidate for gas-phase experiments bearing on the Jahn–Teller (JT) effect (JTE), but many experiments were done in the liquid and in solution as well. The electronic absorption spectrum, − vibrational spectrum, − photoelectron spectrum (PES), − magnetic deflection spectrum, electron paramagnetic resonance (EPR) spectrum, − nuclear magnetic resonance spectrum, electric deflection, electric dipole moment, electron diffraction, − and magnetic susceptibility ,,,, have all been studied, sometimes with respect to the JTE, sometimes not.…”

Section: Introduction and Reviewmentioning

confidence: 99%

Jahn–Teller Effect in VCl₄

et al. 2013

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A theoretical study is made of the Jahn-Teller and other properties of vanadium tetrachloride. Relativistic effective core potentials and corresponding valence spin-orbit operators are used with Gaussian atomic orbitals to compute self-consistent-field and spin-orbit configuration-interaction wave functions. Energy-surface parameters, electronic excitation energies, vibronic energy levels, and g factors are computed. Electron correlation is shown to have a substantial effect on the Jahn-Teller properties. As have others, we find the Jahn-Teller effect in VCl4 to be of the dynamic form.

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