1967
DOI: 10.1002/pssb.19670190137
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Nuclear Magnetic Resonance and Mössbauer Effect Study of Sn119 in Rare Earth‐Tin Intermetallic Compounds

Abstract: The nuclear magnetic resonance and Mossbauer effect of Sn119 have been studied in the cubic intermetallic compounds RSn, (R = La, Ce, Pr, Nd, Sm, and Yb). Both the isotropic and anisotropic components of the Knight shift were determined in the temperature range 77 to 400 OK. In the cases of l'rSn, and NdSn, in which the shift measurements are proportional to the magnetic susceptibility, the results may be understood in terms of the Ruderman-Kittel-Kasuya-Yosida t,heory, with an exchange interaction, I' ; = -0.… Show more

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Cited by 69 publications
(8 citation statements)
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“…There Is a substantial temperature independent Knight shift in ErMn^ and TmMng and no temperature dependence of the Knight shift. This Is strikingly different from the case of the rare earth 1ntermetal11c compounds with Sn (36,37), Al (38,39), P, As, Sb, and BI (10), all those that have been studied heretofore. This Is also different from the case of the beryllium-based Laves phase intermetallic compounds, (40), and V^X compounds investigated by Clogston and Jaccarino (41) and discussed by Bennett e_t a]_.…”
Section: Electric Field Gradient Calculations and Discussioncontrasting
confidence: 64%
“…There Is a substantial temperature independent Knight shift in ErMn^ and TmMng and no temperature dependence of the Knight shift. This Is strikingly different from the case of the rare earth 1ntermetal11c compounds with Sn (36,37), Al (38,39), P, As, Sb, and BI (10), all those that have been studied heretofore. This Is also different from the case of the beryllium-based Laves phase intermetallic compounds, (40), and V^X compounds investigated by Clogston and Jaccarino (41) and discussed by Bennett e_t a]_.…”
Section: Electric Field Gradient Calculations and Discussioncontrasting
confidence: 64%
“…The Knight shifts Kf(T) a t the nonmagnetic site in both SmAL, 12, 231 and SmSn, [13,24] have been observed to be anomalous in the sense that the curvature of the temperature dependence as well as the sign at low temperatures are reversed as compared to the free-ion behaviour, and that the cross-over is suppressed (see Fig. 5, as compared to Pig.…”
Section: Anomalous Knight Shift In Snia12 and Smsn3mentioning
confidence: 99%
“…For example, Jones [206] has tabulated the nonmagnetic site , Knight shift results of rare earth intermetallic compounds in terms of cf. The same results [205,[218][219][220][221][222][223][224][225][226][227][228][229][230] are plotted in a different form in figure 31, namely in terms of ~ == H' errlH~~. Atomic hype rfine behavior is thus normalized out, providing a crude estimate, in J1-B, of the spin moment residing at a nonmagnetic site due to the local moment disturbance.…”
Section: Intermetallic Compoundsmentioning
confidence: 99%