This paper using a method of catalytic adsorption combined with dielectric barrier discharge plasma which added to hydrocarbon gases. The different background gases, different dielectric properties and different pore sizes of the hydrolysis coke on the denitrification performance was studied. The effect of the coaction of plasma and the different properties of the removal of NO in flue gas was investigated, and the catalytic mechanism of the synergistic effect of plasma and hydrocarbon gas was discussed. The results shown that: The denitrification rate was significantly affected by plasma power and the initial concentration of NO; the reaction was restrained by the presence of oxygen and greatly promoted by the hydrocarbon gases. The permittivity of the catalyst has a great influence on the activity and the porous structure of the catalyst can obviously promote the reaction when the low temperature plasma combined with hydrocarbon gases.