Novel Two-dimensional Network Based on Amino-acid-octamolybdate Bridged by Second Metals: {M(H2O)3(pro)Mo4O13}2？H2O (pro = proline, M = Co, Ni, Cu, Zn)

Wu, Xiao; Lu, Can Zhong; Xia, Chang Kun; Chen, Shu Mei; Liu, Jiu Hui; Chen, Li Juan; Yang, Wen

doi:10.5012/bkcs.2006.27.8.1206

Cited by 7 publications

(1 citation statement)

References 16 publications

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“…Furthermore, there is extensive literature in the synthesis and characterisation of POM-based complexes that use amino acids and short peptides as ligands, which has been covered in different review articles. 29,44,45 Since the seminal work of Crans and co-authors, 46,47 the study of these structures and how POMs and amino acids and peptides interact has paved the way to a better understanding of the interaction of POMs and proteins, especially relevant for the development of biological applications.…”

Section: Ionic Pom–peptide Hybridsmentioning

confidence: 99%

Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications

et al. 2023

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Section: Ionic Pom–peptide Hybridsmentioning

confidence: 99%

Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications

et al. 2023

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Synthesis of Chiral MOF‐74 Frameworks by Post‐Synthetic Modification by Using an Amino Acid

Gheorghe

Strudwick

Dawson

et al. 2020

Chemistry A European J

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The synthesis of chiral metal-organic frameworks (MOFs)i sh ighly relevant for asymmetric heterogenous catalysis, yet very challenging. Chiral MOFsw ith MOF-74 topology were synthesised by using post-synthetic modification with proline. Vibrational circular dichroism studies demonstrate that prolinei st he source of chirality.T he solvents used in the synthesis play ak ey role in tuning the loading of proline and its interaction with the MOF-74 framework. In N,N'-dimethylformamide, proline coordinates monodentate to the Zn 2 + ions withint he MOF-74 framework, whereasi ti s only weakly bound to the frameworkw hen using methanol as solvent. Introducing chirality within the MOF-74f ramework also leads to the formation of defects, with both the organic linkera nd metal ions missing from the framework. The formationo fd efects combined with the coordination of DMF and prolinew ithin the framework leads to ap ore blockinge ffect. This is confirmed by adsorption studies and testingo ft he chiral MOFs in the asymmetric aldol reaction betweenacetone and para-nitrobenzaldehyde.

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Synthesis, physicochemical characterizations, and photocatalytic behaviors of Ni x K2Mo4O13 systems

Kassem

2013

Res Chem Intermed

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Novel Two-dimensional Network Based on Amino-acid-octamolybdate Bridged by Second Metals: {M(H2O)3(pro)Mo4O13}2？H2O (pro = proline, M = Co, Ni, Cu, Zn)

Cited by 7 publications

References 16 publications

Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications

Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications

Synthesis of Chiral MOF‐74 Frameworks by Post‐Synthetic Modification by Using an Amino Acid

Synthesis, physicochemical characterizations, and photocatalytic behaviors of Ni x K2Mo4O13 systems

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