Novel tribochemically active metal chelates of aromatic azo ligands

Бурлов, А. С.; Ураев, А. И.; Лысенко, К. А.; Chigarenko, G. G.; Ponomarenko, A. G.; Matuev, P. V.; Николаевский, С. А.; Garnovskaya, E. D.; Бородкин, Г. С.; Гарновский, А. Д.

doi:10.1134/s1070328406090119

Cited by 8 publications

(2 citation statements)

References 9 publications

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“…On the other hand, azo compounds are one of the most important commercial and industrial compounds for paints, textiles, plastics and metal surface. [6][7][8][9] Also, they play an important role in other practical uses such as biological reactions, 10 optical storage technologies 11 and photo electronic effects. [12][13][14] In the most cases, azo compounds should be in solid state, but their intrinsic tendency towards aggregation 15 is a * For correspondence major technical barrier which nanometerization process could resolve it.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of dark brown single-walled carbon nanotubes and their characterization by HSQC-NMR

et al. 2013

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We report here a simple and effective approach to the covalent attachment of single-walled carbon nanotubes (SWCNTs) and azo compounds. The functionalized SWCNTs prepared (through a radical mechanism) have been used for a diazonium coupling reaction. The results showed that the chemical method used has improved the processability and solubility of the carbon nanotubes. The dark brown SWCNTs obtained which can produce a yellow colour in organic solvents were characterized by different spectroscopic analyses. Heteronuclear single quantum coherence spectra (13 C-1 H HSQC) have been used to detect the carbon nanotube allylic protons. The morphology of the main product has been shown by scanning electron microscopy (SEM).

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Section: Introductionmentioning

confidence: 99%

Synthesis of dark brown single-walled carbon nanotubes and their characterization by HSQC-NMR

et al. 2013

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“…Luminescence of heteronuclear lanthanide complexes of type 172 was observed in IR region [91]. Among other applications of coordination compounds, we would like to mention their use in creation of new metalocomplex additives to lubricants, providing the effect of wear less friction [106][107][108]. In particular, easily accessible complexes of o-azomethines and hydrazones with copper and molybdenum are effective as additive.…”

Section: Polyfunctional Materialsmentioning

confidence: 99%

Coordination Aspects in Modern Inorganic Chemistry

Garnovskii¹,

Sennikova²,

Kharisov³

2009

TOICJ

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Main types of coordination compounds in modern inorganic chemistry are discussed. Principal synthesis techniques for metal complexes and the problem of competitive coordination of ambident hard-soft ligands are discussed. A considerable attention is paid to polyfunctional materials, obtained on the basis of coordination compounds, especially molecular magnetics, organic light-emitting devices, and chemosensors.

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An Experimental and Theoretical Study on Influence of H‐bonding on the Synthesized Azo Derivatives Structures

Amiri¹,

Haghdadi²,

Jagadeesan³

et al. 2012

J Chinese Chemical Soc

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We have reported a simple and efficient reaction for the synthesis of some new functionalized azo structures which were prepared by electron deficient acetylenic compounds in the presence of triphenylphosphine. The characterization of the synthesized azo compounds has been determined by FTIR, UV-Vis, 1 H NMR, 13 C NMR and Mass spectroscopic techniques. The influence of H-bonding on the products has been shown by different experimental analysis. Also, the regioselectivity of the reaction, tautomerization equilibrium and the stability of products was investigated using DFT calculations at the B3LYP/6-31G level of theory.

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Novel tribochemically active metal chelates of aromatic azo ligands

Cited by 8 publications

References 9 publications

Synthesis of dark brown single-walled carbon nanotubes and their characterization by HSQC-NMR

Synthesis of dark brown single-walled carbon nanotubes and their characterization by HSQC-NMR

Coordination Aspects in Modern Inorganic Chemistry

An Experimental and Theoretical Study on Influence of H‐bonding on the Synthesized Azo Derivatives Structures

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