Novel Three-Component Coupling Using Aluminum Tris(2,6-diphenylphenoxide) (ATPH): The Same Synthetic Strategy Leads totrans- andcis-Jasmonates

Abstract

One-pot three-component coupling [1] is an important procedure in organic synthesis and provides a powerful and rapid means for construction of the prostaglandin [2] and jasmonate [3] families. Here we report on a novel strategy for three-component coupling (Scheme 1), which involves the Scheme 1. Three-component coupling using ATPH. TBS tert-butyldimethylsilyl.