Novel synthetic route for (parent) phosphetanes, phospholanes, phosphinanes and phosphepanes

Reichl, Stephan; Baláȥs, Gábor; Scheer, Manfred

doi:10.1039/d3sc00580a

Chem. Sci.

2023

DOI: 10.1039/d3sc00580a

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Novel synthetic route for (parent) phosphetanes, phospholanes, phosphinanes and phosphepanes

Stephan Reichl

Gábor Baláȥs

Manfred Scheer

Abstract: A novel synthetic route for (parent) phosphorus-containing cycloalkanes such as phosphetanes, phospholanes, phosphinanes and phosphepanes is reported. By using [K(dme)2]2[Cp*Fe(η4 P5)] (I) in combination with α,ω dibromoalkanes CnH2nBr2 [n =...

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Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis

Chen,

Liu,

Huangfu

et al. 2023

Chemistry A European J

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Organophosphorus compounds (OPCs) are widely used in many fields. However, traditional synthetic routes in the industry usually involve multistep and hazardous procedures. Therefore, it's of great significance to construct such compounds in an environmentally‐friendly and facile way. Herein, a photoredox catalytic method has been developed to construct novel phosphoryltriacetates. Using fac‐Ir(ppy)3 (ppy=2‐phenylpyridine) as the photocatalyst and blue LEDs (456 nm) as the light source, white phosphorus can react with α‐bromo esters smoothly to generate phosphoryltriacetates in moderate to good yields. This one‐step approach features mild reaction conditions and simple operational process without chlorination.

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Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis

Chen,

Liu,

Huangfu

et al. 2023

Chemistry A European J

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Notizen aus der Chemie

Bande¹,

Blasco²,

Dierkes³

et al. 2023

Nachr Chem

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Controlled introduction of functional groups at one P atom in [Cp*Fe(η⁵-P₅)] and release of functionalised phosphines

et al. 2023

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Novel synthetic route for (parent) phosphetanes, phospholanes, phosphinanes and phosphepanes

Abstract: A novel synthetic route for (parent) phosphorus-containing cycloalkanes such as phosphetanes, phospholanes, phosphinanes and phosphepanes is reported. By using [K(dme)2]2[Cp*Fe(η4 P5)] (I) in combination with α,ω dibromoalkanes CnH2nBr2 [n =...

Cited by 3 publications

References 25 publications

Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis

Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis

Notizen aus der Chemie

Controlled introduction of functional groups at one P atom in [Cp*Fe(η⁵-P₅)] and release of functionalised phosphines

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Product

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Novel synthetic route for (parent) phosphetanes, phospholanes, phosphinanes and phosphepanes

Abstract: A novel synthetic route for (parent) phosphorus-containing cycloalkanes such as phosphetanes, phospholanes, phosphinanes and phosphepanes is reported. By using [K(dme)2]2[Cp*Fe(η4 P5)] (I) in combination with α,ω dibromoalkanes CnH2nBr2 [n =...

Cited by 3 publications

References 25 publications

Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis

Direct Synthesis of Phosphoryltriacetates from White Phosphorus via Visible Light Catalysis

Notizen aus der Chemie

Controlled introduction of functional groups at one P atom in [Cp*Fe(η5-P5)] and release of functionalised phosphines

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Controlled introduction of functional groups at one P atom in [Cp*Fe(η⁵-P₅)] and release of functionalised phosphines