Abstract:Polycyclic aromatic hydrocarbons (PAHs) are an important family of molecules in science and technology. Amino‐substituted PAHs are promising building blocks to create attractive molecules for materials science. However, the synthetic limitations have hampered to produce diverse structures of amino‐substituted PAHs. Here we describe a novel efficient synthetic method to access amino‐substituted PAHs through the electrocyclization of highly reactive keteniminium species. We demonstrated the synthesis of various … Show more
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