We
demonstrate an important approach to correlate Purcell factor
(PF) and surface plasmon-coupled emission (SPCE) enhancements with
the use of finite-difference time-domain (FDTD) simulations and time-correlated
single-photon counting (TCSPC) studies of a radiating dipole in cermet
nanocavities. We observed >50-fold fluorescence enhancement with
high
directionality and polarization of Rhodamine 6G (Rh6G) emission trapped
in the nanocavity created between the titanium-based ceramic nanoparticle
and metallic silver thin film. Compositional variation with hybrid
nanoparticles, TiC0N1 (TiN), TiC0.5N0.5 (TiCN), and TiC1N0 (TiC), brought
about enhanced PFs and tunable fluorescence enhancements that were
used for mobile-phone-based detection of tryptophan with nanomolar
sensitivity. We hope that this study opens the door to next-gen plasmonics
with the ability to tune and enhance the hot-spot electromagnetic
field intensity of alternative plasmonic materials, as hybrid synergy
spacers in the SPCE platform.