2007
DOI: 10.1002/cjoc.200790298
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Novel Properties of Photochromic Spirooxazine Nanoparticles

Abstract: The nanoparticles of a spirooxazine (SPO) and its photomerocyanine (PMC) were prepared through the reprecipitation method. Two distinct features were observed. One is that the decaying lifetime for PMC nanoparticles was 600 times of that for the dispersed molecules, and the other is that the fluorescence intensity of SPO nanoparticles was enhanced by 240 times of that of the dispersed monomer.

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Cited by 7 publications
(7 citation statements)
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“…Fluorescence emission from both the closed and the open form of nanoparticles of a spirooxazine have been analyzed [22]. Recently, attempts to create photoswitches with nanostructures have led to remarkable results.…”
Section: Introductionmentioning
confidence: 99%
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“…Fluorescence emission from both the closed and the open form of nanoparticles of a spirooxazine have been analyzed [22]. Recently, attempts to create photoswitches with nanostructures have led to remarkable results.…”
Section: Introductionmentioning
confidence: 99%
“…The growing development of nanotechnologies has increased the variety of investigations about spirooxazines [22][23][24]. Fluorescence emission from both the closed and the open form of nanoparticles of a spirooxazine have been analyzed [22].…”
Section: Introductionmentioning
confidence: 99%
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“…The photo-cyclization in nanoparticles was greatly depressed by the restricted molecular mobility and twisted conformations. SO (6'-hydroxy-5-methoxy-1,3,3-trimethyl-spiro[indoline-2,2'-naphtho[1,2-b]-1,4,2-oxazine]) nanoparticles had an average diameter of 150 nm and 220 nm, respectively, prepared by the reprecipitation method [69]. The absorption band of MC nanoparticles gradually widened and the maximum absorption wavelength showed a slight bathochromic shift compared to the monomer of MC with increasing the particle size.…”
Section: Preparation Methodsmentioning
confidence: 99%
“…The evolution of the fluorescence ratio can be followed in photochromic systems where the photoisomers emit in different wavelength ranges. Reprecipitated MC nanoparticles displayed 240 times enhanced fluorescent emission intensity, which was attributed to the combined effects of deactivation of nonradiation process and enhancement of energy transfer, both of which were the result of the much more densely packed molecules exerted by aggregation [69]. Self-assembled dithienylethene with 3,4,5-tris(dodecyloxy)benzoic acid enhanced and red-shifted the fluorescence of the nanoparticles due to [75] hydrogen bond formation between pyridine and carboxylic acid groups, thus displaying an excellent solid fluorescent switch.…”
Section: Fluorescence Of a Photochromementioning
confidence: 99%