Electrically conductive polypyrrole-zirconium(IV) phosphate (PPy-ZrP) cation exchange nanocomposites have been synthesized for the first time by in situ chemical oxidative polymerization of pyrrole in the presence of zirconium(IV) phosphate (ZrP). Fourier Transform Infra-red spectroscopy (FTIR), field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, differential thermal analysis, derivative thermogravimetry and elemental analysis were used to characterize PPy-ZrP cation exchange nanocomposite. The composite showed good ion-exchange capacity (1.60 meq g -1 ), DC electrical conductivity (0.33 S cm -1 ) and isothermal stability in terms of DC electrical conductivity retention under ambient condition up to 100°C. PPy-ZrP cation exchangenanocomposite-based sensor was fabricated for the detection of ammonia vapours of aqueous ammonia. The resistivity of the nanocomposites increases on exposure to high-concentration ammonia vapours at room temperature (25°C). The rate of reaction for ammonia vapour-sensing on PPy-ZrP was observed as second order.