Novel planar chiral phosphite: Preparation and use in the synthesis of Pd(II) complexes and in Pd-catalyzed allylic alkylation

Tsarev, V. N.; Konkin, Stanislav I.; Loim, N. M.; Kelbysheva, E. S.; Popova, Lyudmila N.; Petrovskii, P. V.; Davankov, V. A.; Gavrilov, K. N.

doi:10.1134/s1070328407090060

Cited by 6 publications

(1 citation statement)

References 24 publications

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“…In 2007, the above-mentioned ferrocenyliminophosphite ligands 81 (Figure ) were applied in the Pd-catalyzed allylic substitution of 1,3-diphenyl-3-acetoxyprop-1-ene with several nucleophiles (ee’s up to 60%). The Pd/ 81f catalytic system provided good enantioselectivities (up to 80%), albeit with moderate regioselectivity (41% in favor of the branched product) in the allylic substitution of monosubstituted substrate 1-(4-chlorophenyl)allyl methyl carbonate. , …”

Section: Asymmetric Pd-allylic Substitutionmentioning

confidence: 98%

Phosphite-Containing Ligands for Asymmetric Catalysis

et al. 2010

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Section: Asymmetric Pd-allylic Substitutionmentioning

confidence: 98%

Phosphite-Containing Ligands for Asymmetric Catalysis

et al. 2010

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Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

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Zagorevskii

2011

Patai's Chemistry of Functional Groups

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This review (782 references) represents an exhaustive up‐to‐date survey of literature on mass spectrometry and gas‐phase ion chemistry of organomanganese complexes. Fundamental physico‐chemical characteristics of organomanganese ionic species, as well as the gas‐phase reactions resulting in the dissociation or formation of manganese‐carbon bond(s) are examined. Circa 300 examples of ion/molecule reactions characterizing the reactivity of Mn + , positively or negatively charged manganese clusters, as well as neutrals, cations and anions of various Mn‐containing species (including coordinatively unsaturated ones) are summarized. A variety of studies involving tandem mass spectrometry, neutralization‐reionization mass spectrometry, collision‐induced dissociation, multiple‐photon dissociation, IRMPD spectroscopy and theoretical calculations for organomanganese ion structure characterization are discussed. Additionally, analytical applications of mass spectrometric techniques to the characterization of compounds containing a MnC bond are reviewed. These include a number of relatively simple mononuclear complexes, polynuclear clusters, complexes incorporating organometallic units bridged with organic fragment(s), bifunctional compounds containing organometallic and classical Werner‐type coordination sites, fullerenes or planar polyaromatic hydrocarbons with an organomanganese fragment attached to them, manganospiralenes, manganoscorpionates, supramolecular entities, cymantrene‐peptide bioconjugates, etc.

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Cyclic and Non-Cyclic Pi Complexes of Manganese

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Emslie

2022

Comprehensive Organometallic Chemistry IV

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Novel planar chiral phosphite: Preparation and use in the synthesis of Pd(II) complexes and in Pd-catalyzed allylic alkylation

Cited by 6 publications

References 24 publications

Phosphite-Containing Ligands for Asymmetric Catalysis

Phosphite-Containing Ligands for Asymmetric Catalysis

Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

Cyclic and Non-Cyclic Pi Complexes of Manganese

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