Novel nanoarchitecture of 3D ion transfer channel containing nanocomposite solid polymer electrolyte membrane based on holey graphene oxide and chitosan biopolymer

Hassan, Mehadi; Brist, Afshana Afroj; He, X. T.; Trifkovic, Milana; Bobrov, Gleb; Lu, Qingye

doi:10.1016/j.cej.2023.143159

Cited by 8 publications

(2 citation statements)

References 101 publications

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“…The Li‐LiFePO 4 full cell shows stable cycling performance at 0.1 C (with a loading of 3 mg cm −2 ), and the specific capacity of the Li‐S full cell is still > 610 mAh g −1 at 60 °C after cycling for 300 cycles at 0.2 C. Similarly, Lu et al. [ 168 ] introduced graphene oxide into a polymer to create a flexible, self‐supporting, and ultrathin (80 um) SPE membrane. The novel three‐dimensional ionic transport paths in the SPE membrane, which are homogeneous and strongly interconnected, can facilitate ionic transport, and as a result, the RT ionic conductivity of SPE membrane is as high as 2.76 × 10 −3 S cm −1 , comparable to that of liquid electrolytes.…”

Section: Sse At Membrane Scalementioning

confidence: 69%

“…Although the solution casting method has been widely used for the large‐scale preparation of polymer‐based SSEs due to the simplicity and maturity of the process, the ability to incorporate a variety of additives as needed, the ease of preparing composite solid electrolytes with oxide/sulfide SSEs, and the ease of infiltration into porous and skeletal materials, the method has been prominent in CPEs in particular due to the integration of the advantages of each of the SPEs and inorganic SSEs. [ 170–172 ] There are five main structural designs studied, namely free‐standing SSE, [ 159–169 ] skeleton supporting SSE, [ 173–194 ] SSE with low tortuosity, [ 195–198 ] electrode‐supporting SSE [ 199–201 ] and in situ polymerization. [ 182,202–208 ] However, it is worth noting that the solution casting method is mainly based on SPE for the preparation and design of CSE, and the introduction of SPE will force the ASSB to operate at high temperatures, in addition, the complete filling of pores in the skeleton is a challenge, too little will lead to the limitation of the performance of composite solid electrolyte, and too much will affect the energy density of the battery.…”

Section: Sse At Membrane Scalementioning

confidence: 99%

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Challenges and Solutions of Solid‐State Electrolyte Film for Large‐Scale Applications

Huang,

Li,

Fan

et al. 2024

Advanced Energy Materials

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Solid‐state lithium‐ion batteries are widely accepted as the promising next‐generation energy storage technology due to higher energy density and improved safety compared to conventional lithium‐ion batteries with liquid electrolytes. Large‐area solid‐state electrolyte (SSE) films with adequate thickness control, improved ionic conductivity, and good interfacial contact can reduce internal resistance, increase the real energy density of batteries, and reduce manufacturing costs. Optimization of SSE properties at the particle scale and large‐scale preparation of SSE films are key to the development of high‐performance solid‐state lithium‐ion batteries and their industrialization. Therefore, this paper provides a comprehensive review of SSE, covering both particle‐level features like the effects of particle size, density, and air stability on the electrochemical performance, as well as four major routes for large‐scale preparation and relevant strategies for structural optimization of SSE films. In addition, the effects of large‐area SSE films on the electrochemical performance of solid‐state batteries and their applications in pouch solid‐state lithium‐ion battery systems are discussed in detail. Finally, the design principles of SSE particles and SSE films are summarized and the development direction of thin SSEs is envisaged.

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Section: Sse At Membrane Scalementioning

confidence: 69%

Section: Sse At Membrane Scalementioning

confidence: 99%

Challenges and Solutions of Solid‐State Electrolyte Film for Large‐Scale Applications

Huang,

Li,

Fan

et al. 2024

Advanced Energy Materials

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Unveiling Confinement Engineering for Achieving High‐Performance Rechargeable Batteries

Lv,

Luo,

Liu

et al. 2024

Advanced Materials

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The confinement effect, restricting materials within nano/sub‐nano spaces, has emerged as an innovative approach for fundamental research in diverse application fields, including chemical engineering, membrane separation, and catalysis. This confinement principle recently presents fresh perspectives on addressing critical challenges in rechargeable batteries. Within spatial confinement, novel microstructures and physiochemical properties have been raised to promote the battery performance. Nevertheless, few clear definitions and specific reviews are available to offer a comprehensive understanding and guide for utilizing the confinement effect in batteries. This review aims to fill this gap by primarily summarizing the categorization of confinement effects across various scales and dimensions within battery systems. Subsequently, the strategic design of confinement environments is proposed to address existing challenges in rechargeable batteries. These solutions involve the manipulation of the physicochemical properties of electrolytes, the regulation of electrochemical activity and stability of electrodes, and insights into ion transfer mechanisms. Furthermore, specific perspectives are provided to deepen the foundational understanding of the confinement effect for achieving high‐performance rechargeable batteries. Overall, this review emphasizes the transformative potential of confinement effects in tailoring the microstructure and physiochemical properties of electrode materials, highlighting their crucial role in designing novel energy storage devices.This article is protected by copyright. All rights reserved

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Nanocomposite design for solid-state lithium metal batteries: Progress, challenge, and prospects

Chen,

Xu,

Yang

et al. 2024

Advanced Nanocomposites

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Novel nanoarchitecture of 3D ion transfer channel containing nanocomposite solid polymer electrolyte membrane based on holey graphene oxide and chitosan biopolymer

Cited by 8 publications

References 101 publications

Challenges and Solutions of Solid‐State Electrolyte Film for Large‐Scale Applications

Challenges and Solutions of Solid‐State Electrolyte Film for Large‐Scale Applications

Unveiling Confinement Engineering for Achieving High‐Performance Rechargeable Batteries

Nanocomposite design for solid-state lithium metal batteries: Progress, challenge, and prospects

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