Novel d- and f-metal phthalocyaninates based on 4-(2,4,5-trichlorophenoxy)phthalonitrile. Synthesis, spectroscopic and fluorescent properties

Botnar, A. A.; Tikhomirovа, T. V.; Nalimova, Kseniya; Erzunov, Dmitry; Razumov, Mikhail; Вашурин, А. С.

doi:10.1016/j.molstruc.2019.127626

Cited by 20 publications

(4 citation statements)

References 32 publications

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“…Phthalocyanines, as a result of their structural features and the possibility of introducing almost any functional moieties to their periphery, have found wide application in areas of societal and industrial importance such as catalysis, optics, medicine, light industry, etc. (Botnar et al, 2020(Botnar et al, , 2021. Substituted phthalocyanines, which attract the most attention, however, are obtained from phthalonitriles with various fragments in the 3 and 4 positions.…”

Section: Chemical Contextmentioning

confidence: 99%

Crystal structures of 4-(2/3-methoxyphenoxy)phthalonitrile

Erzunov

Rassolova

Rumyantcev³

et al. 2023

Acta Cryst E

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The syntheses and crystal structures are reported of 4-phenoxy-substituted phthalonitriles with methoxy groups in the ortho- and meta-positions of the terminal benzene rings, respectively, namely, 4-(2-methoxyphenoxy)phthalonitrile and 4-(3-methoxyphenoxy)phthalonitrile, both C15H10N2O2. The https://journals.iucr.org/e/issues/2023/03/00/molecular structure was determined using the single-crystal X-ray diffraction method. It is shown that short contacts play a more decisive role in the molecular packing compared to van der Waals interactions.

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Section: Chemical Contextmentioning

confidence: 99%

Crystal structures of 4-(2/3-methoxyphenoxy)phthalonitrile

Erzunov

Rassolova

Rumyantcev³

et al. 2023

Acta Cryst E

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“…В этой связи разработка подходов к синтезу таких соединений является ключевым направлением химии металлофталоцианинов и перспективных материалов на их основе [96]. Металлокомплексы фталоцианинов магния, кобальта, меди и цинка получают путем сплавления соответствующего нитрила с солью металла (схема 5) [97][98][99][100][101][102][103][104][105][106][107].…”

Section: синтез и спектральные свойства феноксизамещенных металлофтал...unclassified

“…Ранее нами было отмечено также появление дополнительной полосы поглощения для комплекса цинка, содержащего на периферии трихлорфеноксигруппы (4м) [106]. При рассмотрении ЭСП в литературе в ранних работах отмечаются противоречивые взгляды по интерпретации полосы поглощения в области 740-750 нм, тогда как в настоящее время принято считать, что изменение ЭСП таких комплексов в хлороформе связано с протонированием следами HCl, а не с самосборкой.…”

Section: синтез и спектральные свойства феноксизамещенных металлофтал...unclassified

“…В работах [98,106,108,109] представлены данные по синтезу металлокомплексов с редкоземельными элементами. Синтез преимущественно проводили темплатной конденсацией замещенных фталонитрилов с солями лантанидов (Lu, Er, Gd, Nd) в кипящем растворителе в присутствии DBU (cхема 7).…”

Section: синтез и спектральные свойства феноксизамещенных металлофтал...unclassified

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Chemistry of Liquid Systems and Functional Materials Based on Coordination Compounds of Linear and Cyclic Polypyrroles

2023

Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.

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The review presents a generalization of research on the chemistry of solutions and materials based on linear and cyclic polypyrrole compounds carried out at the Department of Inorganic Chemistry of the Ivanovo State University of Chemistry and Technology. The review focuses on key areas related to synthetic approaches to the preparation of boron complexes with pyrrole derivatives, as well as complexes of a wide range of metals of the periodic system with substituted derivatives of the phthalocyanine ligand. Spectroscopic, luminescent, acid-base properties of synthesized compounds and their practical application in sensor systems are considered separately. In addition, the possibilities of obtaining hybrid and functional materials, including derivatives of borondipyrrins and tetrapyrrole macroheterocyclic compounds, which have increased catalytic and biological activity in liquid-phase processes are shown. For citation: Vashurin A.S., Bobrov A.V., Botnar A.A., Bychkova A.N., Gornukhina O.V., Grechin O.V., Erzunov D.A., Kovanova M.A., Ksenofontova K.V., Kuznetsov V.V., Lefedova O.V., Latypova A.R., Litova N.A., Marfin Yu.S., Pukhovskaya S.G., Tarasyuk I.A., Tikhomirova T.V., Rumyantsev E.V., Usoltsev S.D., Filippov D.V. Chemistry of liquid systems and functional materials based on coordination compounds of linear and cyclic polypyrroles. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2023. V. 66. N 7. P. 76-97. DOI: 10.6060/ivkkt.20236607. 6840j.

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