Novel conversions of a multifunctional, bio-sourced lactone carboxylic acid
Trinadh Kaicharla,
Sangjun Lee,
Ruiqin Wang
et al.
Abstract:The plant-derived compounds furfuryl alcohol and itaconic anhydride are known to undergo a Diels-Alder reaction at room temperature and in bulk to efficiently give an alkene-containing lactone carboxylic acid. Reported here is the conversion of this substance to a variety of derivatives via hydrogenation, epoxidation, or halolactonization reactions. Most notable is the formation of a set of three related acrylate or methacrylate esters (see graphical abstract) produced by direct acylative ring opening of ether… Show more
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