Herein, the CO 2 capture performance of a thermal swing adsorption (TSA) process, equipped with adsorbent-packed heat exchangers, was investigated taking the e ective use of waste heat into account. Two typical CO 2 adsorbents-CaA and NaX zeolites-were examined with regard to their CO 2 adsorption properties from a simulated dry exhaust gas containing 9.5 vol% CO 2 and 90.5 vol% N 2 . The e ects of the hot water temperature supplied to the adsorber and the regeneration air ow rate on the separation performance were investigated, as a function of the adsorption/desorption switching time. Increasing the regeneration temperature was observed to improve the separation performance, and a regeneration temperature of 80°C, yielded a ve-fold increase in the CO 2 concentration when compared with the feed gas at the optimal adsorption/desorption switching interval. A TSA process incorporating an adsorbent-packed heat exchanger is evidently an e ective means of enriching CO 2 , based on decreasing the regeneration of air by internal heating and removal of heat by internal cooling. The separation behaviors of both zeolites are similar, except that the CO 2 concentration in the desorbed gas and the recovery ratio of CaA, at a shorter adsorption/desorption interval, was somewhat larger than that of NaX. These ndings suggest that the adsorption rate of CaA is largely dependent on the adsorbed uptake volume. Reducing the regeneration air ow rate to one fortieth of the original value further increased the CO 2 concentration at the desorption outlet, while lowering the CO 2 recovery ratio. Additionally, the time pro les of desorption outlet gas volume and CO 2 concentration indicated that the desorption outlet CO 2 concentration momentarily reached >70%. Furthermore, the ndings also clari ed the rapid desorption rate of the adsorbed N 2 , which was almost completed within the initial desorption period, and which decreased the averaged CO 2 concentration over the regeneration period.