Novel carbon materials obtained by reactions of C60 fullerene with phosphorus at high temperature

Phosphorus-containing carbons: Preparation, properties and utilization

“…Another reason may be the theoretically demonstrated ability of the phosphorus atoms in a substitutional position to chemisorb oxygen, which leads to the formation of P-O bonds [294]. This explanation is supported by the experimentally observed formation of phosphate structures in phosphorus-containing carbons obtained from oxygen-free sources like graphite and black phosphorus [271], fullerene C 60 and red phosphorus [245], carbon monolith and red phosphorus [246] or by chemical vapor deposition of triphenylphosphine [295].…”

“…The maximum amounts of phosphorus achieved by this method were 15 wt% for a carbon obtained by modification of fullerene with red phosphorus [245] and 6.5 wt% for the modification of a coconut shell activated carbon with phosphoric acid [281].…”

“…10) [237]. Modification of fullerene C 60 with red phosphorus in the temperature range 650-950 °C resulted in the formation of phosphorus-containing nanocrystalline graphitic structures [245]. A maximum amount of phosphorus (15 wt%) was introduced at 800 °C.…”

“…ammonium hexafluorophosphate [243], ionic liquids (1-butyl-3-methlyimidazolium hexafluorophosphate) [244], red phosphorus [245,246], or white phosphorus [247].…”

Different states of carbon produced by high-energy plasmochemistry synthesis

“…New spatial forms of carbon -fullerenes, nanotubes, nanowires and nanofibers have attracted significant interest since the time of their discovery due to their unique physicochemical and mechanical properties [1][2][3]. Much investigation has been carried out in this field in the recent years.…”