In this project, a simple, low-cost and rapid procedure based on dispersive liquid-liquid microextraction (DLLME) technique coupled with high performance liquid chromatography-ultraviolet detector (HPLC-UV) has been used for the extraction and determination of styrene in aqueous solutions. Several factors, such as type of extraction and dispersive solvents and their volumes, salt addition, and pH were optimized. Under optimal conditions, the recoveries of styrene for tea and water samples spiked with 10 and 15 ng mL −1 were in the range of 91.4-97.8 %, whereas the temperature was set at 0, 4, 20, 70 and 91°C for 15, 30, 60, 1440, and 14,400 min. The linear range was obtained in the interval of 1.86-50 ng mL −1 . The limits of detection (S/N = 3) and quantitation (S/N = 10) were 0.6 and 1.86 ng mL −1 , respectively. The relative standard deviations (RSDs) for three replicated analysis of styrene in aqueous samples ranged from 0.01 to 0.3 %.