2008
DOI: 10.1016/j.molliq.2008.07.009
|View full text |Cite
|
Sign up to set email alerts
|

Novel binary eutectic mixtures based on imidazole

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

2
66
0

Year Published

2011
2011
2022
2022

Publication Types

Select...
5
5

Relationship

0
10

Authors

Journals

citations
Cited by 144 publications
(68 citation statements)
references
References 31 publications
2
66
0
Order By: Relevance
“…24 This DES, based on TEMACl and imidazole, remained liquid, albeit highly viscose, even at -24 °C, while the DES based on imidazole and choline chloride has been reported to have a melting point of 56 °C with the same molar ratio as was used here. 25 Because of its easy preparation from commercially available chemicals and its improved liquid range (according to the supplier, the melting points of imidazole and TEMACl are 88-91 °C and 282-284 °C respectively), this DES was chosen as a potential reaction medium for the succinylation of GWP. Both chemicals are also considered safe, and imidazole has previously been investigated as a green solvent for the dissolution of starch 26 and a recyclable solvent in biomass fractionation.…”
Section: Resultsmentioning
confidence: 99%
“…24 This DES, based on TEMACl and imidazole, remained liquid, albeit highly viscose, even at -24 °C, while the DES based on imidazole and choline chloride has been reported to have a melting point of 56 °C with the same molar ratio as was used here. 25 Because of its easy preparation from commercially available chemicals and its improved liquid range (according to the supplier, the melting points of imidazole and TEMACl are 88-91 °C and 282-284 °C respectively), this DES was chosen as a potential reaction medium for the succinylation of GWP. Both chemicals are also considered safe, and imidazole has previously been investigated as a green solvent for the dissolution of starch 26 and a recyclable solvent in biomass fractionation.…”
Section: Resultsmentioning
confidence: 99%
“…The main advantage of this ionic liquid compared with common ionic liquids is its ease of preparation; choline chloride only needs to be mixed with metal chloride or a hydrogen bond donor at an elevated temperature by stirring until they melt into liquid form. A high yield (> 99 wt%) could be obtained economically with this approach due to 100% reaction mass efficiency (Hou et al 2008). The physical, as well as chemical properties of these ionic liquids are similar to air-and water-stable ionic liquids and have some superior characteristics with wide liquid-range (Abbott et al 2004).…”
Section: Introductionmentioning
confidence: 99%
“…This involved literature review [10][11][12][13][14] ; identification of suitable material for eutectic mixture.…”
Section: Methodsmentioning
confidence: 99%