Novel approach to reaction-rate based determinations by use of transient redox effects

Report

“…A narrow definition of the method has been adopted to keep this article within bounds. Thus, several important closely related methods have been omitted, notably the work of Mottola et al (43)(44)(45)(46)) with a recycling system and that of Pungor et al (47,48) on potential measurement, both of which have helped to open up an examination of the potentialities of nonsegmented CFA.…”

Measurement of Sorption Isotherms with Flow-Through Reactors

“…The primary objective of this work is to describe an alternative flow-through reactor technique for the measurement of sorption isotherms on natural solid materials such as soils. The methodology originated in chemical engineering and analytical chemistry (19,20) and represents a hybrid between a batch and a column experiment. Comparison of this technique with batch and column experiments shows that this method offers an alternative and often more effective means to determine sorption isotherms.…”

Kinetic aspects of analytical chemistry

“…They employ the variable-time approach and report that various glycols in the 10~3 M range can be determined with relative errors of about 0.7% and measurement times of only about 15 to 150 seconds. Dutt and Mottola have devised a novel but simple flow-through cell and flowthrough loop system for repetitive and continuous injection determinations (144). All the necessary reagents are contained in a single reservoir and are continuously circulated at constant flow, through the electrolysis cell.…”