Novel 2D Zn-porphyrin metal organic frameworks revived CdS for photocatalysis of hydrogen production

Construction of a 2D layered BiVO4/zinc porphyrin (ZnTCPP) S-scheme heterostructure boosting photocatalytic N2oxidation performance

“…The strong peak near 400–500 nm is the Soret band, and the several absorption peaks in the range of 500–700 nm can be attributed to the Q bands. 42 The band gap values ( E g ) of the prepared samples are estimated by using the Kubelka–Munk 43 equation shown in Fig. S5,† and the E g values of BVO and ZnTCPP are calculated to be 2.21 and 1.90 eV, respectively.…”

Photoelectroactive metal–organic frameworks

“…Hydrogen generation through photocatalytic reactions is quite attractive. Extensive efforts and impressive achievements have been reported by using MOF-based photocatalysts such as pristine MOFs, 115–119 hybrid MOFs with guest species like metal nanoparticles, 55,93,96,120–125 metal sulfides, 51,52,126–128 metal oxides, 54,129–132 MXenes, 133 g-C 3 N 4 , 134,135 and MOF derivatives. 136,137…”

Synthesis and Design of Hybrid Metalloporphyrin Polymers Based on Palladium (II) and Copper (II) Cations and Axial Complexes of Pyridyl-Substituted Sn(IV)Porphyrins with Octopamine

“…Coordination polymers based on metal complexes of tetrapyrrole macrocyclic compounds represent a special group of self-organized systems that combine their structural fragments through non-covalent interactions [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 ]. Such interactions are reversible and easily controlled by various external influences.…”

“…Therefore, the coordination self-assembly is a convenient tool to create stable and controllable architectures by the self-organization of metal and organic components with electronic and geometric complementarity. Different functional substituents, the type of organic fragments binding, the metal nature, and the length of the linking fragments provide a variety of framework structure types and areas of their potential application [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 ]. The construction of supramolecular porphyrin scaffolds is still little studied, but it is undoubtedly an urgent scientific problem, the solution of which will to get closer to understanding the life processes of nature.…”