Notizen: Addukte von Fulminato-Metall-Komplexen mit Bortrifluorid

Beck, W.; Feldl, Klaus

doi:10.1515/znb-1965-0322

Cited by 29 publications

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“…The first results on the identification of amber were the work of professors C. W. Beck [13][14], E. K. Tratman [15], Dr. H. J. Plenderleith and Dr. M. H. Hey [16]. For the first time, spectra characterizing the structure of amber were identified using IR-spectroscopy.…”

Section: Introductionmentioning

confidence: 99%

Raman scattering spectra of amber

Verkhovskaia

Prokopenko

2020

E3S Web Conf.

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The Raman spectra of amber (succinite) of different transparency levels of the Palmniken Deposit of Kaliningrad of Russia were obtained using the Fourier Transform–Raman spectroscopy method, which allows obtaining real and elemental compositions. It was found that succinite (amber) is an organic unsaturated carbon - chain homopolymer with different valence oscillations of aliphatic CH2 and CH3 groups, containing heteroatoms C=C and CH in the main chain with valence in RNS=CH2 and deformation in trans RHC=CHR' oscillations with chemical side chains of up to 8 subgroups. Three main connections were experimentally identified on the obtained Raman spectra, which can be used as characteristic features for identification and diagnostics of succinite of the Palmniken Deposit. Practical significance. The proposed method may be of interest for chemistry, materials science and research related to identification processes. The performed research can be used in the synthesis of high-molecular compounds, in issues related to the development and distribution of various applications of organic materials.

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Section: Introductionmentioning

confidence: 99%

Raman scattering spectra of amber

Verkhovskaia

Prokopenko

2020

E3S Web Conf.

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“…Infrared spectral data and conductivities in dimethylsulfoxide were recorded for most of these compounds. The anhydrous Fe(phen) 2 (CNO) 2 and the corresponding bipyridyl complex can add 1 mole of BF 3 per mole of fulminate ligand to form yellowish-brown adducts (53).…”

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confidence: 99%

Fulminates: A Literature Survey

Rosenwasser¹

1965

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Azido-Komplexe von Mangan(II) und Palladium(II)

1965

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und Tetracarbonyltrimethylsilylisonitril-eisen (4) zu isoiieren, das rnit der von Seyferth [3] dargestellten Verbindung iibereinstimmte.(0C)dFe-C -N -SiR3 ( 4 ) Unseres Wissens sind die Reaktionen von ( I ) rnit Fe(CO), oder Ni(C0)4 die ersten Umsetzungen von Metallcarbonylen, bei denen keine Verdrangung des CO, sondern eine Substitution des Carbonylsauerstoffs ohne Spaltung der Metall-Kohlenstoff-Bindung erfolgt. Die Isolierung von (4) spricht ferner dafur, daR Trimethylsilylcyanid bei der Synthese [3] von (4) aus Fe(CO)5 und R3SiCN als Isonitril reagiert und daR fur diese heutzutage vornehmlich als Cyanid formulierte Verbindung mindestens ein Gleichgewicht m e R3Si-C=N: 2 R3Si-N=C: mit leicht wandernder Trimethylsilylgruppe angenonimen werden muR. Eingegangen am 26. Marz 1965 [Z 9521

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Notizen: Addukte von Fulminato-Metall-Komplexen mit Bortrifluorid

Cited by 29 publications

References 0 publications

Raman scattering spectra of amber

Raman scattering spectra of amber

Fulminates: A Literature Survey

Azido-Komplexe von Mangan(II) und Palladium(II)

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