For a family of long-wave unstable thin-film equations, we prove existence of non-negative weak solutions blowing-up in a finite time. Specifically, building these solutions from initial data with negative energy, we show that their L ∞ -norms go to infinity as t → T * > 0, T * < ∞. In addition, using the Bourgain's type approach, we obtain qualitative information about the blow-up and prove mass concentration phenomenon.