Nonlocal Soft Plasmonics in Planar Homogeneous Multilayers

Abstract

Plasmonics is the study of resonant oscillations of free electrons in metals caused by incident electromagnetic radiation. Surface plasmons can focus and steer light on the subwavelength scale. Apart from metals, plasmonic phenomena can be observed in soft matter systems such as electrolytes which we study here. Resonant charge oscillations can be induced for ions in solution, however, due to their larger mass, they are plasmon-active in a lower frequency regime and on a larger wavelength scale. Our investigation focuses on spatial confinement which allows increasingly strong charge interactions and gives rise to nonlocality or spatial dispersion effects. We derive and discuss the nonlocal optical response of ionic plasmons using a hydrodynamic two-fluid model in a planar homogeneous three-layer system with electrolyte-dielectric interfaces. As in metals, we observe the emergence of additional longitudinal propagation modes in electrolytes which causes plasmonic broadening. Studying such systems enables us to identify and understand plasmonic phenomena in biological and chemical systems.