In material science, half filled 3d orbital of transition metals is essentially an important factor controlling characteristics of alloys and compounds. This paper presents a result of the challenge of excitation of inner-core electron system with long lifetime of zinc films. The advanced zinc films with excited inner-core electron, 3d n (n = 9, 8). We report experimental results of XPS measurements of 9 points in the sample along vertical direction, respectively. The most pronounced futures are existence of satellites, which are about 4 eV higher than the main lines. According to the charge transfer mechanism proposed by A. Kotani and K. Okada, it was clarified that the origins of these peaks are c3d 9 L for the main peak and c3d 9 for the satellite, respectively. From the energy difference, δE B , and peak intensity ratio, I + /I − , between c3d 9 and c3d 10 L, the energy for charge transfer, ∆, and mixing energy, T, were estimated. In the region where the intensity of c3d 10 L becomes large, ∆ becomes small, 1.2 < ∆ < 2.7, and T becomes small, too, 0.1 < T < 0.9, respectively. In this calculation, we supposed U dc = 5.5 eV and U dd = 5.5 eV. In the analysis along vertical direction, intensity profile of Zn3d 9 showed odd functional symmetry and that of Zn3d 10 L showed even functional symmetry. Only the intensity profile of C1s (288 eV) showed the same spatial correlation with Zn3d 9 . In our experiment, the sample also showed high mobility of the constituting elements. These suggest that charge conservation in excited zinc atom suggests combination between Zn3d 9 and C 2− .