2007
DOI: 10.1063/1.2710437
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Nonlinear spin wave magnetization of solution synthesized Ni nanoparticles

Abstract: The magnetic properties of Ni nanoparticles synthesized using a soft chemical method followed by heat treatment in H 2 atmosphere have been studied in detail. The powder consists of pure Ni with no additional phase and the average crystallite size is 30± 5 nm, determined using the modified Scherer relation. The crystallites tend to agglomerate into large particles of sizes 50-100 nm, as observed by transmission electron microscopy. The saturation magnetization is found to be 46.42 emu g −1 at 5 K, about 80% of… Show more

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Cited by 16 publications
(7 citation statements)
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References 27 publications
(21 reference statements)
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“…The lattice constant has been determined from all three XRD peaks and for each sample separately. The average of 0.3529 ¡ 0.0005 nm is consistent with the literature, namely 0.3524 nm for bulk Ni 35,36 being expanded up to 0.354 nm in small size, strained grains. 36 The intensity ratio of the (111) to the (200) peak heights increases from 2.32 (cyan curve) to 3.13 (green curve) when the morphology of nanostructures changes from particle to wire, indicating a preferential orientation of Ni grains in the wires.…”
Section: Size Control and Microstructuresupporting
confidence: 90%
“…The lattice constant has been determined from all three XRD peaks and for each sample separately. The average of 0.3529 ¡ 0.0005 nm is consistent with the literature, namely 0.3524 nm for bulk Ni 35,36 being expanded up to 0.354 nm in small size, strained grains. 36 The intensity ratio of the (111) to the (200) peak heights increases from 2.32 (cyan curve) to 3.13 (green curve) when the morphology of nanostructures changes from particle to wire, indicating a preferential orientation of Ni grains in the wires.…”
Section: Size Control and Microstructuresupporting
confidence: 90%
“…This drop is likely associated with the onset of discontinuities in the film resulting in an increased surface contribution with high spin disorder and consequently reduced spin-wave stiffness. This has been observed in clusters of Ni nanoparticles [30]. In Fig.…”
Section: Experiments and Resultsmentioning
confidence: 66%
“…All dimensions are given in nm. significantly reduced saturation magnetization [44,45,46,47,48]. This e↵ect is usually associated with strong magnetic disorder and spin-glass like behaviour at the nanoparticle surface [49,50,51,52].…”
Section: A Phenomenological Model For the Macroscopic Structure Of Thmentioning
confidence: 99%