The head-on collision of dust acoustic solitary waves (DASWs) in an unmagnetized dusty plasma with single electrons, two-temperature ions, variable dust charge is investigated using the extended Poincaré-Lighthill-Kuo (PLK) method. The effects of the dust charge fluctuation and two temperature ion are studied. It is found that the dust charge fluctuation and two temperature ion have the significant role on the phase shift.