Afforestation has been proposed as an effective approach to reduce atmospheric carbon (C) and mitigate climate change (Lewis et al., 2019;Peng et al., 2014). Globally, the area of afforested land has increased from 168 to 278 million hectares from 1990 to 2015 (FAO, 2015;Keenan et al., 2015), which is estimated to sequester ∼860 Gt CO 2 in plant biomass and soil at the end of the century (Kreidenweis et al., 2016). However, several recent studies have indicated that afforestation do not necessarily enhance C sequestration due to strong nitrogen (N) and phosphorus (P) limitations on plant growth with time after afforestation (Deng et al., 2017;Nolan et al., 2021). In particular, soil P cycling may become decoupled with C and N following afforestation because P is derived predominantly from the weathering of parent material, whereas C and nitrogen (N) can enter the ecosystem through biological fixation (Delgado-Baquerizo et al., 2013). This decoupling provokes imbalances between C, N, and P in soils, with important implications for the long-term sustainability of afforested ecosystems. Therefore, it is essential to evaluate soil P availability (plant-available inorganic P) for C sequestration following afforestation, in order to advance accurate prediction for future C uptake by afforested lands.Increases in plant growth and biomass stocks could induce gradual transfer of P from the mineral soil to aboveground plant biomass and lead to an overall decline in soil total P content at top soils following afforestation (