Nonlinear and Emissive {[MIII(CN)6]3–···Polyresorcinol} (M = Fe, Co, Cr) Cocrystals Exhibiting an Ultralow Frequency Raman Response
Katarzyna Jędrzejowska,
Jedrzej Kobylarczyk,
Dominika Tabor
et al.
Abstract:Optically active functional noncentrosymmetric architectures might be achieved through the combination of molecules with inscribed optical responses and species of dedicated tectonic character. Herein, we present the new series of noncentrosymmetric cocrystal salt solvates (PPh 4 ) 3 [M(CN) 6 ](L) n •msolv (M = Cr(III), Fe(III), Co(III); L = polyresorcinol coformers, multiple hydrogen bond donors: 3,3′,5,5′-tetrahydroxy-1,19-biphenyl, DiR, n = 2, or 5′-(3,5-dihydroxyphenyl)-3,3″,5,5″-tetrahydroxy-1,19:3′,1″-te… Show more
Molecular materials are playing a pivotal role in the advancement of prospective THz technologies. Herein, we have prepared nine isostructural coordination complexes of general formula [LnIII(H2O)3][AgI(CN)2]3 (LnAg, Ln = La,...
Molecular materials are playing a pivotal role in the advancement of prospective THz technologies. Herein, we have prepared nine isostructural coordination complexes of general formula [LnIII(H2O)3][AgI(CN)2]3 (LnAg, Ln = La,...
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