Nonequilibrium, diffusional effects on reversible dissociation of excited acids

Power Law Behavior in the Asymptotic Relaxation of Reversible Diffusion-Influenced ReactionA+B⇄ABPerturbed by Photolysis

“…In recent years much effort [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20] has been devoted to the theoretical study of reversible diffusion-influenced reactions schematically written by A 1 B : AB. When the concentrations of A and AB are much less than that of B, the kinetics is pseudo-first-order and thus the reaction dynamics of A and AB molecules can be assumed to be statistically independent of each other.…”